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An unidenti ed Japanese species of the same genus yielded several cembranoids (75 78), all having seven-membered lactone systems. Their structures were elucidated based on spectral data and chemical correlations.40 Several other seven-membered cembranoid lactones, (1E,3E,8S,11Z)-4,8-dimethyl-1-isopropyl7-oxo-cyclotetradeca-1,3,11-triene and its 7R and 7S-hydroxyderivative (79 82), were isolated from an Australian species (Figure 6-7).41 Two novel irregular cembranoids possessing a 13-membered carbocyclic skeleton, sarcotol (83), and sarcotal acetata (84) were reported from another unidenti ed Sarcophyton species (Figure 6-8), whose structures were determined by spectroscopic and single-crystal x-ray analyses and chemical conversion.42,43 Two new cytotoxic tetraterpenes, methylsarcophytotate (85) and methylchlorosarcophytoate (86), were isolated from the species of Japanese seawater.44 Another novel tetraterpenoid, methylisosartortuate (88), was reported being isolated from S. tortuosum; its structure was determined by spectral data and con rmed by x-ray studies.45 The same species yielded one more unique tetracyclic tetraterpenoid, methylsartortuate (89), and its structure was con rmed by x-ray diffraction.46 A new biscembranoid, methylneosartotuate (87), and a novel bisepoxidecembranoid 66 along with a known compound, methylsarcoate (65), were isolated from an Australian species of S. tortuosum; their structures were elucidated by 1-D and 2-D NMR spectral data.35 A unique new tetraterpenoid 90 was also isolated from the Chinese species S. tortuosum, and its structure was established by comparison of its spectra with its derivatives (Figure 6-9).47 excel 2010 barcode font How to create Code 128 barcodes in Excel on Mac?
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