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9-1f Crosslinking A consideration of the effect of crosslinking on polymer reactivity is important since some polymer reactions are performed to achieve crosslinking for speci c applications (Sec 9-2), while other polymer reactions are carried out on previously crosslinked polymers (Secs 9-10 through 9-13) For crosslinked polymers, the concentration of small molecule reactant inside the polymer domains can be lower than outside because of a low degree of swelling This results from a high degree of crosslinking and/or the use of a poor solvent for the polymer The diffusion coef cients for solvent and small-molecule reactant often also decrease under these conditions The effects of different solvents on polymer reactivity can be quite dramatic For the SN2 reaction of pyridine with various alkyl halides, the ratios of the reaction rates in 2-pentanone, toluene, and n-heptane are approximately 7 : 2 : 1.

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BACKGROUND AND INTEREST RATES DURING THE COLONIAL AND REVOLUTIONARY PERIODS The American colonies were outposts of an old civilization. Their physical environment was primitive, but their political and financial traditions were not. Therefore, the history of colonial credit and interest rates is not a history of innovation but rather a history of adaptation. The colonists from England brought with them seventeenth-century English attitudes toward credit and interest. Commercial loans at interest were considered entirely moral and legal and a normal part of business life. Personal debt for consumption was frowned upon as imprudent. Moderate interest rates were desirable, while high interest rates were usurious and were forbidden by law. The English usury laws had established the legal maximum at 6%. This 6% tradition crossed the Atlantic and in most of the states survived until the 1950 s. The colonies also adopted the harsh English laws in favor of creditors. This combination of rigorous enforcement of debt and legal maximum rates of interest comes down from Hammurabi through Rome, through seventeenth-century England, to the modern United States. The different Greek tradition of laissez faire was revived by seventeenth-century Holland and adopted by nineteenth-century England. Interest rate legislation in the colonies was by no means uniform, nor are state usury laws uniform today. In 1661 Massachusetts fixed the legal maximum rate at 8%; in 1692 Maryland adopted 6%. A 6% legal maximum was soon established in most of the colonies. In Virginia 5% became the

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This is the expected order for an SN2 reaction between neutral substrate and reactant molecules, where increased solvent polarity assists in the development of charge separation in the transition state For the corresponding reaction of crosslinked poly(4-vinylpyridine), the 2-pentanone : toluene : n-heptane reaction rate ratio is approximately 10 : 10 : 1 [Grieg and Sherrington, 1978] The high reactivity in toluene is a consequence of this solvent being a good solvent (as is 2-pentanone) for poly(4-vinylpyridine), while n-heptane is a poor solvent The extent of swelling of the crosslinked polymer is high in 2-pentanone and toluene, which results in higher local concentrations of the small molecule reactant in the polymer domains Presumably, the diffusion coef cients are also higher in these solvents relative to n-heptane The rate of epoxidation of cyclohexene with perbenzoic acid decreases with increasing solvent polarity The epoxidation by poly(peracrylic acid) shows the opposite trend.

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Aug 14, 2018 · Steps to merge multiple PDF files programmatically: Create a new C# console application project. Install the Syncfusion.Pdf.WinForms NuGet package as reference to your .NET Framework applications from NuGet.org. Include the following namespaces in the Program.cs file.

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A polar solvent causes the polar polymer to swell to a greater extent and the reaction rate is increased due to a higher local concentration of cyclohexene [Takagi, 1975] High crosslink densities may severely depress polymer reactivity as a result of large decreases in swelling and diffusion rate within the polymer Diffusion control in a polymer reaction can be detected by the inverse dependence of rate on polymer particle size (radius for spherical particle, thickness for lm or sheet) [Imre et al, 1976; Sherrington, 1988] 9-1g Steric Effects.

Polymer reactivity can be sterically hindered under certain conditions when the functional group is close to the polymer chain or in a sterically hindered environment or reaction involves a small molecule reactant that is bulky. Several examples illustrate this effect:

maximum (473) While such legislation does not tell what the prevailing rates of interest were in the colonies, it does indicate the rates that leading citizens considered normal or reasonable According to Benjamin Franklin, commercial interest rates in Pennsylvania in the latter half of the eighteenth century were between 6% and 10% (473) Hard money was very scarce throughout the early colonial period There was no domestic mining of gold or silver European coins were brought over in small quantities by colonists, but were soon shipped home in return for needed manufactures (474) American communities were largely self-sufficient Nevertheless, some goods, such as metal products, salt, paper, medicines, and ammunition had to be bought; the cost of such purchases is estimated at $10 $50 a year per family (475) Exports did not equal imports, and hence there was a drain of specie out of the colonies.

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